1-Butyl-3-methyl-2-(diphenylphosphino)imidazalolium hexafluorophosphate as an efficient ligand for recoverable palladium-catalyzed Suzuki-Miyaura reaction in neat water
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| Title: | 1-Butyl-3-methyl-2-(diphenylphosphino)imidazalolium hexafluorophosphate as an efficient ligand for recoverable palladium-catalyzed Suzuki-Miyaura reaction in neat water |
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| Authors: | Khosravi, Faezeh | Gholinejad, Mohammad | Lledó, David | Grindlay, Guillermo | Nájera, Carmen | Sansano, Jose M. |
| Research Group/s: | Síntesis Asimétrica (SINTAS) | Espectrometría Atómica Analítica (GEAA) |
| Center, Department or Service: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatología | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Keywords: | Suzuki coupling | Biaryls | Palladium | Water | Green process |
| Knowledge Area: | Química Orgánica | Química Analítica |
| Issue Date: | 15-Nov-2019 |
| Publisher: | Elsevier |
| Citation: | Journal of Organometallic Chemistry. 2019, 901: 120941. doi:10.1016/j.jorganchem.2019.120941 |
| Abstract: | The 1-butyl-3-methyl-2-(diphenylphosphino)imidazalolium hexafluorophosphate is prepared and used as a water-soluble ligand in the Suzuki-Miyaura reaction. This ligand and palladium chloride generates a new active catalyst for the Suzuki coupling reaction between aryl iodides or bromides with arylboronic acids in neat water. This catalyst can be recycled and reused for the coupling reaction of 4-bromobenzonitrile with phenylboronic acid for at least six runs with low decreasing in catalytic activity. |
| Sponsor: | The authors are grateful to Institute for Advanced Studies in Basic Sciences (IASBS) Research Council and Iran National Science Foundation (INSF-Grant number of 97021804) for support of this work. We also gratefully acknowledge financial support from the Spanish Ministerio de Ciencia e Innovaci on (MICINN) (projects CTQ2010-20387 and Consolider Ingenio 2010, CSD2007-00006), the Spanish Ministerio de Economía y Competitividad (MINECO) (projects CTQ2013-43446-P and CTQ2014-51912-REDC), the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigaci on (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2016-76782-P and CTQ2016-81797-REDC), the Generalitat Valenciana (PROMETEO2009/039 and PROMETEOII/2014/017), the University of Alicante. |
| URI: | http://hdl.handle.net/10045/96888 |
| ISSN: | 0022-328X (Print) | 1872-8561 (Online) |
| DOI: | 10.1016/j.jorganchem.2019.120941 |
| Language: | eng |
| Type: | info:eu-repo/semantics/article |
| Rights: | © 2019 Elsevier B.V. |
| Peer Review: | si |
| Publisher version: | https://doi.org/10.1016/j.jorganchem.2019.120941 |
| Appears in Collections: | INV - SINTAS - Artículos de Revistas INV - GEAA - Artículos de Revistas |
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| File | Description | Size | Format | |
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 2019_Khosravi_etal_JOrganometallicChem_final.pdf | Versión final (acceso restringido) | 854,6 kB | Adobe PDF | Open Request a copy |
 2019_Khosravi_etal_JOrganometallicChem_revised.pdf | Versión revisada (acceso abierto) | 1,23 MB | Adobe PDF | Open Preview |
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