Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering
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http://hdl.handle.net/10045/66484
| Títol: | Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering |
|---|---|
| Autors: | Casco, Mirian Elizabeth | Fernández-Catalá, Javier | Cheng, Yongqiang | Daemen, Luke L. | Ramírez-Cuesta, Anibal J. | Cuadrado-Collados, Carlos | Silvestre-Albero, Joaquín | Ramos-Fernández, Enrique V. |
| Grups d'investigació o GITE: | Materiales Avanzados |
| Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
| Paraules clau: | Breathing | Flexibility | Inelastic Neutron Scattering | Swinging | ZIF-8 |
| Àrees de coneixement: | Química Inorgánica |
| Data de publicació: | 23-de març-2017 |
| Editor: | Wiley-VCH Verlag GmbH & Co. KGaA |
| Citació bibliogràfica: | ChemistrySelect. 2017, 2(9): 2750-2753. doi:10.1002/slct.201700250 |
| Resum: | Despite the vast number of publication dealing with ZIF-8, the performance of this zeolitic MOF upon adsorption is still a matter of debate. The understanding of its adsorption properties its of great importance to define its potential in aplications such as gas separation, sensing and catalytic processes. Using inelastic neutron scattering (INS) upon exposure to different probe molecules we get further insight about the adsortion performance at cryogenic temperatures, including the possible swinging of the imidazolate linkers. |
| Patrocinadors: | The authors acknowledge financial support from the MINECO projects MAT-2013-45008-P, MAT2016-81732-ERC. EVRF gratefully acknowledge support from MINECO for his Ramón y Cajal grant (RyC-2012-11427) and University of Alicante for the project GRE-13-31. Generalitat Valenciana is acknowledge for support (PROMETEOII/2014/004). This research benefited from use of the VISION beamline (IPTS-15878.1) at ONRL’s Spallation Neutron Source and the VirtES (Virtual Experiments in Spectroscopy) project, (LDRD 7739), which are supported by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy, under Contract No. DE-AC0500OR22725 with UT Battelle, LLC. |
| URI: | http://hdl.handle.net/10045/66484 |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.201700250 |
| Idioma: | eng |
| Tipus: | info:eu-repo/semantics/article |
| Drets: | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
| Revisió científica: | si |
| Versió de l'editor: | http://dx.doi.org/10.1002/slct.201700250 |
| Apareix a la col·lecció: | INV - LMA - Artículos de Revistas |
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 2017_Casco_etal_ChemistrySelect_final.pdf | Versión final (acceso restringido) | 750,69 kB | Adobe PDF | Obrir Sol·licitar una còpia |
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