Selective hydrogenation by novel composite supported Pd egg-shell catalysts
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http://hdl.handle.net/10045/57831
Título: | Selective hydrogenation by novel composite supported Pd egg-shell catalysts |
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Autor/es: | Carrara, Nicolas | Badano, Juan M. | Betti, Carolina P. | Lederhos, Cecilia R. | Rintoul, Ignacio | Coloma, Fernando | Vera, Carlos R. | Quiroga, Mónica E. |
Grupo/s de investigación o GITE: | Materiales Avanzados |
Centro, Departamento o Servicio: | Universidad de Alicante. Servicios Técnicos de Investigación |
Palabras clave: | Pd/composite | Egg-shell catalysts | Selective hydrogenation | Mechanical property improvement |
Fecha de publicación: | 10-feb-2015 |
Editor: | Elsevier |
Cita bibliográfica: | Catalysis Communications. 2015, 61: 72-77. doi:10.1016/j.catcom.2014.12.012 |
Resumen: | Two organic–inorganic mixed phase supports were prepared, comprising an alumina filler and polymers of different chemical nature. Four low loaded Pd catalysts were prepared. Good activities and selectivities were obtained during the hydrogenations of styrene, 1-heptyne and 2,3-butanedione. The catalysts were found to have excellent mechanical properties and could be used in applications needing high attrition resistance and crushing strength. In this sense, processes for fine chemicals using slurry reactors or processes for commodities using long packed beds could advantageously use them. |
Patrocinador/es: | The authors are gratefully indebted to ANPCyT, CONICET, UNL and SECTeI Santa Fe for funding this work. |
URI: | http://hdl.handle.net/10045/57831 |
ISSN: | 1566-7367 (Print) | 1873-3905 (Online) |
DOI: | 10.1016/j.catcom.2014.12.012 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2014 Elsevier B.V. |
Revisión científica: | si |
Versión del editor: | http://dx.doi.org/10.1016/j.catcom.2014.12.012 |
Aparece en las colecciones: | INV - LMA - Artículos de Revistas |
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Archivo | Descripción | Tamaño | Formato | |
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2015_Carrara_etal_CatComm_final.pdf | Versión final (acceso restringido) | 1,79 MB | Adobe PDF | Abrir Solicitar una copia |
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