Sample introduction systems for the analysis of liquid microsamples by ICP-AES and ICP-MS
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http://hdl.handle.net/10045/2752
Títol: | Sample introduction systems for the analysis of liquid microsamples by ICP-AES and ICP-MS |
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Autors: | Todolí Torró, José Luis | Mermet, Jean Michel |
Grups d'investigació o GITE: | Análisis Químico Aplicado |
Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatología | Laboratoire des Sciences et Stratégies Analytiques |
Paraules clau: | ICP-AES | ICP–MS | Aerosol transport phenomena | Microsample analysis | Nebulizer | Spray chamber | Desolvation system |
Àrees de coneixement: | Química Analítica |
Data de publicació: | de març-2006 |
Editor: | Elsevier |
Citació bibliogràfica: | TODOLÍ TORRÓ, José Luis; MERMET, Jean Michel. “Sample introduction systems for the analysis of liquid microsamples by ICP-AES and ICP-MS”. Spectrochimica Acta Part B: Atomic Spectroscopy. Vol. 61, Issue 3 (March 2006). ISSN 0584-8547, pp. 239-283 |
Resum: | There are many fields in which the available sample volume is the limiting factor for an elemental analysis. Over the last ten years, sample introduction systems used in plasma spectrometry (i.e., Inductively Coupled Plasma Atomic Emission Spectrometry, ICP-AES, and Mass Spectrometry, ICP-MS) have evolved in order to expand the field of applicability of these techniques to the analysis of micro- and nanosamples. A full understanding of the basic processes occurring throughout the sample introduction system is absolutely necessary to improve analytical performance. The first part of the present review deals with fundamental studies concerning the different phenomena taking place from aerosol production to analyte excitation/ionization when the liquid consumption rate does not exceed 100μl/min. Existing sample introduction systems are currently far from the ideal and a significant effort has been made to develop new and efficient devices. Different approaches for continuously introducing small sample volumes (i.e., microsamples) have been reviewed and compared in the present work. Finally, applications as well as basic guidelines to select the best sample introduction system according to the sample particularities are given at the end of this review. |
URI: | http://hdl.handle.net/10045/2752 |
ISSN: | 0584-8547 |
DOI: | 10.1016/j.sab.2005.12.010 |
Idioma: | eng |
Tipus: | info:eu-repo/semantics/article |
Revisió científica: | si |
Versió de l'editor: | http://dx.doi.org/10.1016/j.sab.2005.12.010 |
Apareix a la col·lecció: | INV - AQA-CCA - Artículos de Revistas INV - NANOBIOPOL - Artículos de Revistas INV - bioCir - Artículos de Revistas INV - bioCir - Artículos de Revistas |
Arxius per aquest ítem:
Arxiu | Descripció | Tamany | Format | |
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sab 2006 (239).pdf | Versión final (acceso restringido) | 1,29 MB | Adobe PDF | Obrir Sol·licitar una còpia |
Todolí_SAB.pdf | Borrador revisado. Texto (acceso libre) | 452,81 kB | Adobe PDF | Obrir Vista prèvia |
figures.pdf | Borrador revisado. Figuras (acceso libre) | 597,69 kB | Adobe PDF | Obrir Vista prèvia |
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