Branched poly(ionic liquid)‑modifed magnetic nanoparticles as a nitrogen‑rich and hydrophilic support for stabilization of Pd nanoparticles and exploring its catalytic activity
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Title: | Branched poly(ionic liquid)‑modifed magnetic nanoparticles as a nitrogen‑rich and hydrophilic support for stabilization of Pd nanoparticles and exploring its catalytic activity |
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Authors: | Gholinejad, Mohammad | Zareh, Fatemeh | Bagheri, Hossein | Nikfarjam, Nasser | Sansano, Jose M. |
Research Group/s: | Síntesis Asimétrica (SINTAS) |
Center, Department or Service: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Keywords: | Magnetic nanoparticles | Ionic liquid | Reduction | Hydrophilic polymer |
Issue Date: | 22-Apr-2024 |
Publisher: | Springer Nature |
Citation: | Research on Chemical Intermediates. 2024. https://doi.org/10.1007/s11164-024-05268-8 |
Abstract: | A novel magnetic nanocomposite modified with a new branched polymer containing nitrogen-rich ligand moieties was synthesized and used to stabilize Pd nanoparticles. The resulting catalyst was characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, vibrating sample magnetometry, thermogravimetric analysis and energy-dispersive X-ray. The synthesized catalyst has been applied as an efficient catalyst in the reduction of nitro compounds to corresponding amines and reductive degradation of organic dyes such as methyl orange and methyl red. The catalyst showed high stability and reusability for 10 runs without significant loss in catalytic activity. |
Sponsor: | Funding for this study was received from the Ministerio de Ciencia, Innovación y Universidades RED2018-102387-T, PID2019-107268 GB-100, and FEDER, the Generalitat Valenciana IDIFEDER/2021/013. Iran National Science Foundation, 4024819, Ministerio de Ciencia, Innovación y Universidades, RED2018-102387-T, PID2019-107268 GB-100 |
URI: | http://hdl.handle.net/10045/142445 |
ISSN: | 0922-6168 (Print) | 1568-5675 (Online) |
DOI: | 10.1007/s11164-024-05268-8 |
Language: | eng |
Type: | info:eu-repo/semantics/article |
Rights: | © The Author(s), under exclusive licence to Springer Nature B.V. 2024 |
Peer Review: | si |
Publisher version: | https://doi.org/10.1007/s11164-024-05268-8 |
Appears in Collections: | INV - SINTAS - Artículos de Revistas |
Files in This Item:
File | Description | Size | Format | |
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Gholinejad_etal_2024_ResChemIntermed_final.pdf | Versión final (acceso restringido) | 2,66 MB | Adobe PDF | Open Request a copy |
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