Debromination and Reusable Glass Fiber Recovery from Large Waste Circuit Board Pieces in Subcritical Water Treatment
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http://hdl.handle.net/10045/125279
Títol: | Debromination and Reusable Glass Fiber Recovery from Large Waste Circuit Board Pieces in Subcritical Water Treatment |
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Autors: | Gandon-Ros, Gerard | Aracil, Ignacio | Gómez-Rico, María Francisca | Conesa, Juan A. |
Grups d'investigació o GITE: | Residuos, Energía, Medio Ambiente y Nanotecnología (REMAN) | Ingeniería para la Economía Circular (I4CE) |
Centre, Departament o Servei: | Universidad de Alicante. Departamento de Ingeniería Química | Universidad de Alicante. Instituto Universitario de Ingeniería de los Procesos Químicos |
Paraules clau: | Debromination | Waste printed circuit boards | Reusable glass fiber recovery | Subcritical water treatment |
Àrees de coneixement: | Ingeniería Química |
Data de publicació: | 13-de juliol-2022 |
Editor: | American Chemical Society |
Citació bibliogràfica: | ACS Omega. 2022, 7(29): 25422-25432. https://doi.org/10.1021/acsomega.2c02368 |
Resum: | The great economic, social, and environmental interest that favors an effective management of the recycling of waste printed circuit boards (WCBs) encourages research on the improvement of processes capable of mitigating their harmful effects. In this work, the debromination of large WCBs was first performed through a hydrothermal process employing potassium carbonate as an additive. A total of 32 runs were carried out at 225 °C, various CO32–/Br– anionic ratios of 1:1, 2:1, 4:1, and 6:1, treatment times from 30 to 360 min, proportion of submerged WCBs in the liquid of 100, 50, and 25% that corresponded with the use of three WCB sizes of 20 mm × 16.5 mm, 20 mm × 33 mm, and 80 mm × 33 mm, respectively, and solid/liquid ratios of 1:2 and 1:1 g/mL without other metallic catalysts. A debromination efficiency of 50 wt % was reached at only 225 °C (limited by mechanical reasons) and 360 min, using a CO32–/Br– anionic ratio of 4:1 and a solid/liquid ratio of 1:2 for a large WCB with only 25% of its volume submerged in the liquid. This means conservation of water and energy compared to previous studies. A muffle furnace was used later to thermally treat a total of 101 debrominated samples, at constant temperature or following a temperature scaling program. An estimated decrease in resistance to rupture of glass fibers of only around 50% was accomplished by following a temperature scaling program up to 475 °C, obtaining clean glass fibers of large size. The simple techniques proposed to obtain reusable glass fibers from WCBs as large as the size of the reactor allows (as it might be in their original size) could significantly improve interest in the industry. |
Patrocinadors: | Support for this work was granted by the PID2019-105359RB-I00 project and the scholarship BES-2017-080382 from the Ministry of Science and Innovation of Spain and project UAUSTI20-05 from the University of Alicante. |
URI: | http://hdl.handle.net/10045/125279 |
ISSN: | 2470-1343 |
DOI: | 10.1021/acsomega.2c02368 |
Idioma: | eng |
Tipus: | info:eu-repo/semantics/article |
Drets: | © 2022 The Authors. Published by American Chemical Society. Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND 4.0) |
Revisió científica: | si |
Versió de l'editor: | https://doi.org/10.1021/acsomega.2c02368 |
Apareix a la col·lecció: | INV - I4CE - Artículos de Revistas INV - REMAN - Artículos de Revistas |
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Gandon-Ros_etal_2022_ACSOmega.pdf | 7,06 MB | Adobe PDF | Obrir Vista prèvia | |
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