Determination of As, Se, and Hg in fuel samples by in-chamber chemical vapor generation ICP OES using a Flow Blurring® multinebulizer
Please use this identifier to cite or link to this item:
http://hdl.handle.net/10045/69052
Title: | Determination of As, Se, and Hg in fuel samples by in-chamber chemical vapor generation ICP OES using a Flow Blurring® multinebulizer |
---|---|
Authors: | García, Miriam | Aguirre Pastor, Miguel Ángel | Canals, Antonio |
Research Group/s: | Espectroscopía Atómica-Masas y Química Analítica en Condiciones Extremas |
Center, Department or Service: | Universidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatología | Universidad de Alicante. Instituto Universitario de Materiales |
Keywords: | ICP OES | Flow Blurring multiple nebulizer | Multinebulization | Fuels | Trace elements | In-chamber chemical vapor generation |
Knowledge Area: | Química Analítica |
Issue Date: | Sep-2017 |
Publisher: | Springer Berlin Heidelberg |
Citation: | Analytical and Bioanalytical Chemistry. 2017, 409(23): 5481-5490. doi:10.1007/s00216-017-0484-6 |
Abstract: | In this work, a new and simple analytical methodology based on in-chamber chemical vapor generation has been developed for the spectrochemical analysis of commercial fuel samples. A multiple nebulizer with three nebulization units has been employed for this purpose: One unit was used for sample introduction, while the other two were used for the necessary reagent introduction. In this way, the aerosols were mixed inside the spray chamber. Through this method, analyte transport and, therefore, sensitivity are improved in inductively coupled plasma-optical emission spectrometry. The factors (i.e., variables), influencing chemical vapor generation, have been optimized using a multivariate approach. Under optimum chemical vapor generation conditions ([NaBH4] = 1.39%, [HCl] = 2.97 M, total liquid flow = 936 μL min−1), the proposed sample introduction system allowed the determination of arsenic, selenium, and mercury up to 5 μg g−1 with a limit of detection of 25, 140, and 13 μg kg−1, respectively. Analyzing spiked commercial fuel samples, recovery values obtained were between 96 and 113%, and expanded uncertainty values ranged from 4 to 16%. The most striking practical conclusion of this investigation is that no carbon deposit appears on the plasma torch after extended periods of working. |
Sponsor: | The authors would like to thank the Spanish Ministry of Science and Innovation (project n. CTQ2011-23968), the Spanish Ministry of Economy, Industry and Competitiveness (project n. CTQ2016-79991-R) (AEI/FEDER, UE) and Generalitat Valenciana (Spain) (project n. PROMETEO/2013/038) for the financial support, and Agilent Technologies Inc. for the loan of the ICP OES spectrometer. |
URI: | http://hdl.handle.net/10045/69052 |
ISSN: | 1618-2642 (Print) | 1618-2650 (Online) |
DOI: | 10.1007/s00216-017-0484-6 |
Language: | eng |
Type: | info:eu-repo/semantics/article |
Rights: | © Springer-Verlag GmbH Germany 2017 |
Peer Review: | si |
Publisher version: | http://dx.doi.org/10.1007/s00216-017-0484-6 |
Appears in Collections: | INV - SP-BG - Artículos de Revistas |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
2017_Miriam-Garcia_etal_AnalBioanalChem_final.pdf | Versión final (acceso restringido) | 634,2 kB | Adobe PDF | Open Request a copy |
2017_Miriam-Garcia_etal_AnalBioanalChem_revised.pdf | Versión revisada (acceso abierto) | 2,28 MB | Adobe PDF | Open Preview |
2017_Miriam-Garcia_etal_AnalBioanalChem_ESI.pdf | Electronic supplementary information | 2,24 MB | Adobe PDF | Open Preview |
Items in RUA are protected by copyright, with all rights reserved, unless otherwise indicated.