Pinacol Rearrangement and Direct Nucleophilic Substitution of Allylic Alcohols Promoted by Graphene Oxide and Graphene Oxide CO2H
Please use this identifier to cite or link to this item:
http://hdl.handle.net/10045/64767
| Title: | Pinacol Rearrangement and Direct Nucleophilic Substitution of Allylic Alcohols Promoted by Graphene Oxide and Graphene Oxide CO2H |
|---|---|
| Authors: | Gómez-Martínez, Melania | Baeza, Alejandro | Alonso, Diego A. |
| Research Group/s: | Catálisis Estereoselectiva en Síntesis Orgánica (CESO) | Nuevos Materiales y Catalizadores (MATCAT) |
| Center, Department or Service: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Keywords: | Allylic compounds | Carbocations | Graphene | Green chemistry | Rearrangement |
| Knowledge Area: | Química Orgánica |
| Issue Date: | 20-Mar-2017 |
| Publisher: | Wiley-VCH Verlag GmbH & Co. KGaA |
| Citation: | ChemCatChem. 2017, 9(6): 1032-1039. doi:10.1002/cctc.201601362 |
| Abstract: | Graphene oxide (GO) and carboxylic acid functionalized GO (GO–CO2H) have been found to efficiently promote the heterogeneous and environmentally friendly pinacol rearrangement of 1,2-diols and the direct nucleophilic substitution of allylic alcohols. In general, high yields and regioselectivities are obtained in both reactions using 20 wt % of catalyst loading and mild reaction conditions. |
| Sponsor: | Financial support from the University of Alicante (UAUSTI16-03, VIGROB-173), and Spanish Ministerio de Economía y Competitividad (CTQ2015-66624-P) is acknowledged. |
| URI: | http://hdl.handle.net/10045/64767 |
| ISSN: | 1867-3880 (Print) | 1867-3899 (Online) |
| DOI: | 10.1002/cctc.201601362 |
| Language: | eng |
| Type: | info:eu-repo/semantics/article |
| Rights: | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
| Peer Review: | si |
| Publisher version: | http://dx.doi.org/10.1002/cctc.201601362 |
| Appears in Collections: | INV - MATCAT - Artículos de Revistas INV - CESO - Artículos de Revistas INV - AMIC - Artículos de Revistas |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
 2017_Gomez-Martinez_etal_ChemCatChem_final.pdf | Versión final (acceso restringido) | 619,11 kB | Adobe PDF | Open Request a copy |
 2017_Gomez-Martinez_etal_ChemCatChem_accepted.pdf | Accepted Manuscript (acceso abierto) | 4,11 MB | Adobe PDF | Open Preview |
See citations in Google Scholar
Items in RUA are protected by copyright, with all rights reserved, unless otherwise indicated.