Molecular aggregation of naphthalimide organic semiconductors assisted by amphiphilic and lipophilic interactions: a joint theoretical and experimental study
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/63490
Título: | Molecular aggregation of naphthalimide organic semiconductors assisted by amphiphilic and lipophilic interactions: a joint theoretical and experimental study |
---|---|
Autor/es: | Arrechea-Marcos, Iratxe | Echegaray, Paula de | Mancheño, María José | Ruiz Delgado, María del Carmen | Ramos, María del Mar | Quintana, José A. | Villalvilla, José M. | Díaz-García, María A. | López Navarrete, Juan T. | Ponce Ortiz, Rocío | Segura, José L. |
Grupo/s de investigación o GITE: | Física de la Materia Condensada |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Física Aplicada | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | Molecular aggregation | Naphthalimide organic semiconductors | Amphiphilic and lipophilic interactions |
Área/s de conocimiento: | Física Aplicada | Física de la Materia Condensada |
Fecha de publicación: | 3-feb-2017 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | Physical Chemistry Chemical Physics. 2017, 19: 6206-6215. doi:10.1039/C6CP06819G |
Resumen: | Amphiphilic and lipophilic donor–acceptor naphthalimide–oligothiophene assemblies exhibiting almost identical intramolecular properties, but differing in their intermolecular interactions, have been synthesized. Here we analyze the effect of replacing the normally used lipophilic alkyl chains with hydrophilic ones in directing molecular aggregation from an antiparallel to a parallel stacking. This different molecular packing of the amphiphilic, NIP-3TAmphi, and lipophilic, NIP-3TLipo, systems is assessed by electronic spectroscopies, scanning electronic microscopy and DFT quantum-chemical calculations. Theoretical calculations indicate that the presence of amphiphilic interactions promotes a face-to-face parallel arrangement of neighbor molecules, which induces improved electronic coupling and therefore enhances the charge transport ability and photoconducting properties of this type of materials. Time of flight and photoconducting measurements are used to determine the impact of the amphiphilic and lipophilic interactions on their possible performance in optoelectronic devices. |
Patrocinador/es: | We thank the MINECO of Spain (MAT2014-52305-P and MAT2016-77608-C3-2-P) and the UCM-BSCH joint project (GR3/14-910759), for financial support at Complutense University of Madrid. Research at University of Malaga was supported by MINECO (CTQ2015-66897-P) and Junta de Andalucia (P09-4708). R. P. O. and I. A.-M. thank the MINECO of Spain for a “Ramón y Cajal” research contract and for a predoctoral fellowship, respectively. The work performed at the University of Alicante was funded by MINECO through grant no. MAT-2011-28167-C02-01. |
URI: | http://hdl.handle.net/10045/63490 |
ISSN: | 1463-9076 (Print) | 1463-9084 (Online) |
DOI: | 10.1039/C6CP06819G |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © the Owner Societies 2017 |
Revisión científica: | si |
Versión del editor: | http://dx.doi.org/10.1039/C6CP06819G |
Aparece en las colecciones: | INV - Física de la Materia Condensada - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
---|---|---|---|---|
2017_Arrechea_etal_PCCP_final.pdf | Versión final (acceso restringido) | 2,77 MB | Adobe PDF | Abrir Solicitar una copia |
2017_Arrechea_etal_PCCP_accepted.pdf | Accepted Manuscript (acceso abierto) | 982 kB | Adobe PDF | Abrir Vista previa |
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.