Two-dimensional Cu deposition on Pt(100) and stepped surfaces of platinum single crystals
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/53952
Registro completo de metadatos
Campo DC | Valor | Idioma |
---|---|---|
dc.contributor | Electroquímica de Superficies | es |
dc.contributor.author | Molodkina, E.B. | - |
dc.contributor.author | Ehrenburg, M.R. | - |
dc.contributor.author | Danilov, A.I. | - |
dc.contributor.author | Feliu, Juan M. | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Física | es |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Electroquímica | es |
dc.date.accessioned | 2016-03-22T09:30:17Z | - |
dc.date.available | 2016-03-22T09:30:17Z | - |
dc.date.issued | 2016-03-10 | - |
dc.identifier.citation | Electrochimica Acta. 2016, 194: 385-393. doi:10.1016/j.electacta.2016.02.082 | es |
dc.identifier.issn | 0013-4686 (Print) | - |
dc.identifier.issn | 1873-3859 (Online) | - |
dc.identifier.uri | http://hdl.handle.net/10045/53952 | - |
dc.description.abstract | The initial stages of Cu deposition at low overpotentials have been studied on the Pt(100) and Pt(111) basal faces and stepped surfaces Pt(610), Pt(410) of platinum single crystal electrodes. The process includes formation of a Cuad adlayer, an epitaxial monolayer of a two dimensional phase and three dimensional copper crystallites on the (100) terraces, while on the Pt(111) face the two dimensional Cu layer is absent as in this case 3-fold coordination of deposited Cu atoms probably cannot provide sufficient decrease in surface energy of the system. At high enough cathodic overpotentials, the 3D-phase of copper is formed on the monolayer of copper adatoms Pt(111)-Cuad. The Stranski-Krastanov mechanism of nucleation and growth is realized on all the studied electrodes. | es |
dc.description.sponsorship | Financial support from the Russian Foundation for Basic Research (project no. 14-03-00530), MINECO (CTQ2013-44083-P) and Generalitat Valenciana (PrometeoII/2014/013) (Feder, Spain) is gratefully acknowledged. | es |
dc.language | eng | es |
dc.publisher | Elsevier | es |
dc.rights | © 2016 Elsevier Ltd. | es |
dc.subject | Pt(100) | es |
dc.subject | Pt(610) | es |
dc.subject | Pt(410) | es |
dc.subject | Pt(111) | es |
dc.subject | 2-dimensional and 3-dimensional Cu deposition | es |
dc.subject | Sulfuric acid | es |
dc.subject.other | Química Física | es |
dc.title | Two-dimensional Cu deposition on Pt(100) and stepped surfaces of platinum single crystals | es |
dc.type | info:eu-repo/semantics/article | es |
dc.peerreviewed | si | es |
dc.identifier.doi | 10.1016/j.electacta.2016.02.082 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.electacta.2016.02.082 | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2013-44083-P | - |
Aparece en las colecciones: | INV - EQSUP - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
---|---|---|---|---|
2016_Civicos_etal_Tetrahedron_final.pdf | Versión final (acceso restringido) | 570,37 kB | Adobe PDF | Abrir Solicitar una copia |
2016_Civicos_etal_Tetrahedron_accepted.pdf | Accepted Manuscript (acceso abierto) | 563,78 kB | Adobe PDF | Abrir Vista previa |
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.