Cobalt-Impregnated Magnetite as General Heterogeneous Catalyst for the Hydroacylation Reaction of Azodicarboxylates
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Title: | Cobalt-Impregnated Magnetite as General Heterogeneous Catalyst for the Hydroacylation Reaction of Azodicarboxylates |
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Authors: | Pérez Galera, Juana María | Ramón, Diego J. |
Research Group/s: | Nuevos Materiales y Catalizadores (MATCAT) |
Center, Department or Service: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Keywords: | Aldehydes | Azo compounds | Cobalt | Heterogeneous catalysis |
Knowledge Area: | Química Orgánica |
Issue Date: | 13-Oct-2014 |
Publisher: | Wiley-VCH Verlag GmbH & Co. KGaA |
Citation: | Advanced Synthesis & Catalysis. 2014, 356(14-15): 3039-3047. doi:10.1002/adsc.201400207 |
Abstract: | Catalysts consisting of cobalt and nickel impregnated on magnetite have been prepared, characterized and used for the hydroacylation reaction of different azodicarboxylate compounds with aldehydes, using nearly stoichiometric amounts of both reagents in only 3 h. Furthermore, this reaction has been conducted with the smallest amount of catalyst. The cobalt catalyst is stable enough to be removed by magnetic decantation and recycled ten-fold without any detrimental effect on the results. |
Sponsor: | This work was supported by the Spanish Ministerio de Economía y Competitividad (MICINN; CTQ2011-24151) and University of Alicante. J. M.P. thanks the MICINN (FPI program) for her fellowship. |
URI: | http://hdl.handle.net/10045/46302 |
ISSN: | 1615-4150 (Print) | 1615-4169 (Online) |
DOI: | 10.1002/adsc.201400207 |
Language: | eng |
Type: | info:eu-repo/semantics/article |
Rights: | © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
Peer Review: | si |
Publisher version: | http://dx.doi.org/10.1002/adsc.201400207 |
Appears in Collections: | INV - MATCAT - Artículos de Revistas INV - AMIC - Artículos de Revistas |
Files in This Item:
File | Description | Size | Format | |
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2014_Perez_Ramon_ASC_final.pdf | Versión final (acceso restringido) | 828,02 kB | Adobe PDF | Open Request a copy |
2014_Perez_Ramon_ASC_preprint.pdf | Versión revisada (acceso abierto) | 587,02 kB | Adobe PDF | Open Preview |
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