Investigating the influence of surfactants on the stabilization of aqueous reduced graphene oxide dispersions and the characteristics of their composite films
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Título: | Investigating the influence of surfactants on the stabilization of aqueous reduced graphene oxide dispersions and the characteristics of their composite films |
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Autor/es: | Fernández Merino, María Jesús | Paredes Nachón, Juan Ignacio | Villar Rodil, Silvia | Guardia, Laura | Solís Fernández, Pablo | Salinas-Torres, David | Cazorla-Amorós, Diego | Morallon, Emilia | Martínez Alonso, Amelia | Díez Tascón, Juan Manuel |
Grupo/s de investigación o GITE: | Electrocatálisis y Electroquímica de Polímeros |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | Grafenos | Surfactantes | Propiedades electroquímicas |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | 28-oct-2011 |
Editor: | Elsevier |
Cita bibliográfica: | FERNÁNDEZ-MERINO, M.J., et al. “Investigating the influence of surfactants on the stabilization of aqueous reduced graphene oxide dispersions and the characteristics of their composite films”. Carbon. Vol. 50, Issue 9 (Aug. 2012). ISSN 0008-6223, pp. 3184-3194 |
Resumen: | The stabilization of reduced graphene oxide (RGO) sheets in aqueous dispersion using a wide range of surfactants of anionic, non-ionic and zwitterionic type has been investigated and compared under different conditions of pH, surfactant and RGO concentration, or sheet size. The observed differences in the performance of the surfactants were rationalized on the basis of their chemical structure (e.g., alkylic vs. aromatic hydrophobic tail or sulfonic vs. carboxylic polar head), thus providing a reference framework in the selection of appropriate surfactants for the processing of RGO suspensions towards particular purposes. RGO-surfactant composite paper-like films were also prepared through vacuum filtration of the corresponding mixed dispersions and their main characteristics were investigated. The composite paper-like films were also electrochemically characterized. Those prepared with two specific surfactants exhibited a high capacitance in relation to their surfactant-free counterpart. |
Patrocinador/es: | Financial support from the Spanish MICINN (projects MAT2008-05700, MAT2010-15273 and MAT2011-26399) is gratefully acknowledged. M.J.F.-M. and D.S.-T. are indebted to MICINN for their pre-doctoral (FPI) grants. L.G. acknowledges CSIC for a post-doctoral contract (JAE-Doc). |
URI: | http://hdl.handle.net/10045/23247 |
ISSN: | 0008-6223 (Print) | 1873-3891 (Online) |
DOI: | 10.1016/j.carbon.2011.10.039 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Revisión científica: | si |
Versión del editor: | http://dx.doi.org/10.1016/j.carbon.2011.10.039 |
Aparece en las colecciones: | INV - GEPE - Artículos de Revistas |
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Carbon_grafenos.pdf | Versión final (acceso restringido) | 906,1 kB | Adobe PDF | Abrir Solicitar una copia |
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