1. RUA
  2. Research
  3. Espectroscopía Atómica-Masas y Química Analítica en Condiciones Extremas
  4. INV - SP-BG - Artículos de Revistas

Modified MSIS chamber as novel gas-liquid separator coupled with photochemical vapor generation of trace mercury with MP-AES detection

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/136907
StatisticsStatistics
Full metadata record
Full metadata record
DC FieldValueLanguage
dc.contributorEspectroscopía Atómica-Masas y Química Analítica en Condiciones Extremases_ES
dc.contributor.authorStoitsov, Dimitar-
dc.contributor.authorKmetov, Veselin Y.-
dc.contributor.authorCanals, Antonio-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatologíaes_ES
dc.date.accessioned2023-09-04T11:57:20Z-
dc.date.available2023-09-04T11:57:20Z-
dc.date.issued2023-08-30-
dc.identifier.citationJournal of Analytical Atomic Spectrometry. 2023, 38: 1920-1926. https://doi.org/10.1039/D3JA00207Aes_ES
dc.identifier.issn0267-9477 (Print)-
dc.identifier.issn1364-5544 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/136907-
dc.description.abstractNew hyphenation of continuous flow photochemical vapor generator (PVG) to modified multimode sample introduction system (MSIS) used as gas-liquid separator and microwave plasma atomic emission spectrometry (MP-AES) was proposed for analysis of trace mercury. The widened MSIS bottom inlet contributes to the increase of the Hg0 mass transfer in the gas-liquid separator allowing the mercury determination by MP-AES. After optimizing the PVG reactor conditions and MP-AES instrument parameters a limit of detection (LOD) of 0.25 ppb was obtained for Hg2+. The applicability of the PVG-MSIS-MP-AES method was subsequently demonstrated for trace mercury analysis in two soil CRMs - ERM-CC135a (Contaminated Brickworks soil) and CRM005 (Sewage Amended soil).es_ES
dc.description.sponsorshipThis study is financed by the European Union-NextGenerationEU, through the National Recovery and Resilience Plan of the Republic of Bulgaria, project № BG-RRP-2.004-0001-C01.es_ES
dc.languageenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.rights© Royal Society of Chemistryes_ES
dc.subjectPhotochemical vapor generationes_ES
dc.subjectMSISes_ES
dc.subjectMP-AES detectiones_ES
dc.subjectGas-liquid separatores_ES
dc.subjectTrace mercuryes_ES
dc.titleModified MSIS chamber as novel gas-liquid separator coupled with photochemical vapor generation of trace mercury with MP-AES detectiones_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.peerreviewedsies_ES
dc.identifier.doi10.1039/D3JA00207A-
dc.relation.publisherversionhttps://doi.org/10.1039/D3JA00207Aes_ES
dc.rights.accessRightsinfo:eu-repo/semantics/embargoedAccesses_ES
dc.date.embargoEndinfo:eu-repo/date/embargoEnd/2024-08-31es_ES
Appears in Collections:INV - SP-BG - Artículos de Revistas

Files in This Item:
Files in This Item:
File Description SizeFormat 
ThumbnailStoitsov_etal_2023_JAnalAtSpectrom_accepted.pdfEmbargo 12 meses (acceso abierto: 31 ag. 2024)1,02 MBAdobe PDFOpen    Request a copy
ThumbnailStoitsov_etal_2023_JAnalAtSpectrom_final.pdfVersión final (acceso restringido)405,86 kBAdobe PDFOpen    Request a copy
Show simple item record


Items in RUA are protected by copyright, with all rights reserved, unless otherwise indicated.