Hierarchical Assembly of a Micro- and Macroporous Hydrogen-Bonded Organic Framework with Tailored Single-Crystal Size
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Título: | Hierarchical Assembly of a Micro- and Macroporous Hydrogen-Bonded Organic Framework with Tailored Single-Crystal Size |
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Autor/es: | Halliwell, Christopher A. | Dann, Sandra E. | Ferrando-Soria, Jesús | Plasser, Felix | Yendall, Keith | Ramos-Fernández, Enrique V. | Vladisavljević, Goran T. | Elsegood, Mark R.J. | Fernandez, Antonio |
Grupo/s de investigación o GITE: | Materiales Avanzados |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | Crystal Growth | Hierarchical Assembly | Hydrogen-Bonded Organic Frameworks | Macropores | Micropores |
Fecha de publicación: | 26-sep-2022 |
Editor: | Wiley-VCH GmbH |
Cita bibliográfica: | Angewandte Chemie International Edition. 2022, 61(47): e202208677. https://doi.org/10.1002/anie.202208677 |
Resumen: | Porous organic molecular materials represent an emergent field of research in Chemistry and Materials Science due to their unique combination of properties. To enhance their performance and expand the number of applications, the incorporation of hierarchical porosity is required, as exclusive microporosity entails several limitations. However, the integration of macropores in porous organic molecular materials is still an outstanding challenge. Herein, we report the first example of a hydrogen-bonded organic framework (MM-TPY) with hierarchical skeletal morphology, containing stable micro- and macroporosity. The crystal size, from micro to centimetre scale, can be controlled in a single step without using additives or templates. The mechanism of assembly during the crystal formation is compatible with a skeletal crystal growth. As proof of concept, we employed the hierarchical porosity as a platform for the dual, sequential and selective co-recognition of molecular species and microparticles. |
Patrocinador/es: | J.F.-S. thanks “Ramón y Cajal“ program (RYC2019-02794-I), MINECO (Spain) (Projects PID2019−104778GB−I00 and Excellence Unit “Maria de Maeztu” CEX2019−000919−M) and Generalitat Valenciana (SEJI/2020/034). E.V.R.F. thanks Ministerio de Ciencia e innovación (PID2020-116998RB-I00) and Ministerio de Educación y Formación Profesional (PRX21/00407). |
URI: | http://hdl.handle.net/10045/128658 |
ISSN: | 1433-7851 (Print) | 1521-3773 (Online) |
DOI: | 10.1002/anie.202208677 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1002/anie.202208677 |
Aparece en las colecciones: | INV - LMA - Artículos de Revistas |
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