Extended UNIQUAC Thermodynamic Modeling of Aqueous Two-Phase Systems, Water + Salt + Short-Chain Alcohol
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/127206
Título: | Extended UNIQUAC Thermodynamic Modeling of Aqueous Two-Phase Systems, Water + Salt + Short-Chain Alcohol |
---|---|
Autor/es: | Gomis, Alejandro | Fosbøl, Philip L. | Thomsen, Kaj |
Grupo/s de investigación o GITE: | Equilibrio entre Fases |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Ingeniería Química |
Palabras clave: | Extended UNIQUAC thermodynamic modeling | Aqueous two-phase systems | Water + salt + short-chain alcohol |
Fecha de publicación: | 11-sep-2022 |
Editor: | American Chemical Society |
Cita bibliográfica: | Industrial & Engineering Chemistry Research. 2022, 61(37): 14066-14080. https://doi.org/10.1021/acs.iecr.2c01717 |
Resumen: | The extended UNIQUAC activity coefficient model for electrolyte solutions was used for simulating the water + short-chain alcohol (1-propanol, 2-propanol, and tert-butanol) + salt (NaCl, KCl, NH4Cl, Na2SO4, and K2SO4) systems in a wide temperature range (0–100 °C). Experimental data were used for determining the interaction parameters (water + alcohol and alcohol + ion) and the volume and surface area parameters. Parameters for water + ion interactions were taken from previous publications. Equilibrium calculations including SLLV, SLL, SLV, LLV, LV, SV, and SL were performed with the model. The results are largely in agreement with those obtained experimentally. Model parameters previously published for these systems were revised based on new data. |
URI: | http://hdl.handle.net/10045/127206 |
ISSN: | 0888-5885 (Print) | 1520-5045 (Online) |
DOI: | 10.1021/acs.iecr.2c01717 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2022 American Chemical Society |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1021/acs.iecr.2c01717 |
Aparece en las colecciones: | INV - EQF - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Gomis_etal_2022_IndEngChemRes_final.pdf | Versión final (acceso restringido) | 4,87 MB | Adobe PDF | Abrir Solicitar una copia |
Gomis_etal_2022_IndEngChemRes_accepted.pdf | Accepted Manuscript (acceso abierto) | 2,34 MB | Adobe PDF | Abrir Vista previa |
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.