Novel Water Dispersible and Magnetically Recoverable Palladium Nano Catalyst for Room-Temperature Suzuki-Miyaura Coupling Reaction
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http://hdl.handle.net/10045/121373
Título: | Novel Water Dispersible and Magnetically Recoverable Palladium Nano Catalyst for Room-Temperature Suzuki-Miyaura Coupling Reaction |
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Autor/es: | Gholinejad, Mohammad | Mirmohammadi, Soheil | Sansano, Jose M. |
Grupo/s de investigación o GITE: | Síntesis Asimétrica (SINTAS) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Heterogeneous | Magnetic | Palladium | Starch | Suzuki |
Área/s de conocimiento: | Química Orgánica |
Fecha de publicación: | 22-dic-2021 |
Editor: | Wiley-VCH GmbH |
Cita bibliográfica: | ChemistrySelect. 2021, 6(48): 13906-13917. https://doi.org/10.1002/slct.202103589 |
Resumen: | In this work, a new magnetic composite comprising starch, imidazolium and triazol groups is used as a support for stabilization of palladium nanoparticles. This material has been characterized by different techniques showing the presence of small and uniform Pd nanoparticles in about 2 nm size. Measuring contact angle confirmed important role of starch on increasing hydrophilic nature of the catalyst. Using 0.05 mol% of this catalyst aryl iodides or bromides reacted with boronic acids at room temperature in aqueous media and the corresponding products are obtained in very good to excellent yields. Hot filtration and PVPy poisoning tests confirmed the heterogeneous nature of the catalyst. E-factor of the catalyst was found in acceptable range and close to green chemistry standards. This catalyst is magnetically recovered and recycled for 10 consecutive times with small decrease in activity. Also, the robustness of this catalytic system is demonstrated by the characterization of the reused catalyst. |
Patrocinador/es: | The authors are grateful to Institute for Advanced Studies in Basic Sciences (IASBS) Research Council and Iran National Science Foundation (INSF-Grant number of 4003055) for support of this work. We also thankful for financial support to the Spanish Ministerio de Economía y Competitividad (MINECO) (projects CTQ2013-43446-P and CTQ2014-51912-REDC), the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2016-76782-P and CTQ2016-81797-REDC), the Generalitat Valenciana (PROMETEOII/2014/017) and the University of Alicante. |
URI: | http://hdl.handle.net/10045/121373 |
ISSN: | 2365-6549 |
DOI: | 10.1002/slct.202103589 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2021 Wiley-VCH GmbH |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1002/slct.202103589 |
Aparece en las colecciones: | INV - SINTAS - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Gholinejad_etal_2021_ChemistrySelect_final.pdf | Versión final (acceso restringido) | 3,06 MB | Adobe PDF | Abrir Solicitar una copia |
Gholinejad_etal_2021_ChemistrySelect_revised.pdf | Versión revisada (acceso abierto) | 3,66 MB | Adobe PDF | Abrir Vista previa |
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