Bi–Sn nanoparticles for electrochemical denitrification: activity and selectivity towards N2 formation
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Título: | Bi–Sn nanoparticles for electrochemical denitrification: activity and selectivity towards N2 formation |
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Autor/es: | Sanjuán, Ignacio | García Cruz, Leticia | Solla-Gullón, José | Expósito Rodríguez, Eduardo | Montiel, Vicente |
Grupo/s de investigación o GITE: | Electroquímica Aplicada y Electrocatálisis |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica |
Palabras clave: | Electrochemical denitrification | Nitrate | Bismuth | Tin | Nanoparticles |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | 20-abr-2020 |
Editor: | Elsevier |
Cita bibliográfica: | Electrochimica Acta. 2020, 340: 135914. doi:10.1016/j.electacta.2020.135914 |
Resumen: | Electrochemical denitrification is a promising approach to remove NO3− towards its conversion to innocuous N2. In this work, the electrocatalytic performance of Bi, Sn and BixSny carbon-supported nanoparticles (∼10 nm) was evaluated for the selective NO3− electroreduction (NER) to N2. The different electrocatalysts were synthesised using a simple chemical method, physicochemically characterised by TEM-EDS and XPS and, subsequently, air-brushed onto a Toray carbon paper to build electrodes. These electrodes were characterised by SEM-EDS and cyclic voltammetry. Electrolyses were carried out in a slightly alkaline media to find the most active electrocatalyst towards the NO3− removal. Among them, Bi60Sn40/C showed the best results with more than 50% of selectivity to N2 after exhaustive electrolyses, regardless of the cathode potential or the electric charge passed. Other detected non-desired secondary products were N2O, NO2− and NH4+/NH3. The results obtained point out that the combination of Sn and Bi gives rise to higher NER activity and selectivity to N2 than pure Bi and pure Sn. Therefore, these electrocatalysts are not only promising but also cost-effective for future practical applications like electrochemical denitrification of wastewater. Nevertheless, further investigation is still needed in order to assess the optimum operational conditions. |
Patrocinador/es: | I. Sanjuán acknowledges the Ph.D. fellowship granted and the material and human resources provided by the University of Alicante and the company Aguas de Valencia, S.A (UAIND2016-02). JSG acknowledges financial support from VITC (Vicerrectorado de Investigación y Transferencia de Conocimiento) of the University of Alicante (UATALENTO16-02). |
URI: | http://hdl.handle.net/10045/103309 |
ISSN: | 0013-4686 (Print) | 1873-3859 (Online) |
DOI: | 10.1016/j.electacta.2020.135914 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2020 Elsevier Ltd. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.electacta.2020.135914 |
Aparece en las colecciones: | INV - LEQA - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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2020_Sanjuan_etal_ElectrochimActa_final.pdf | Versión final (acceso restringido) | 2,21 MB | Adobe PDF | Abrir Solicitar una copia |
2020_Sanjuan_etal_ElectrochimActa_accepted.pdf | Accepted Manuscript (acceso abierto) | 3,19 MB | Adobe PDF | Abrir Vista previa |
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